Coordination chemistry of thioether-carboranes in polynuclear metal carbonyl cluster complexes. B-H activation of thioether-carboranes by dirhenium carbonyl complexes
نویسندگان
چکیده
منابع مشابه
Studies of the Structures and Bonding of Gold-Bridged Dirhenium Carbonyl Cluster Complexes
The compounds Re2(CO)8(μ-AuPPh3)2, 1, a dimer of Re(CO)4(μ-AuPPh3), and ax,ax-Re2(CO)8(PPh3)2 were obtained from UV−vis radiationinduced decarbonylation of the compound Re(CO)5[Au(PPh3)]. Compound 1 contains two rhenium atoms bridged by two AuPPh3 groups. The complex has 32 valence electrons and is formally unsaturated by the amount of two electrons. The Re−Re bond distance in 1 is unusually sh...
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Gas-phase chemical behaviors of short-lived technetium carbonyl complexes were studied using a low temperature isothermal chromatograph (IC) coupled with a (252)Cf spontaneous fission (SF) source. Fission products recoiled from the (252)Cf SF source were thermalized in a mixed gas containing CO, and then technetium carbonyl complexes were formed from reactions between CO gas and various technet...
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Methods are described for characterising neutral metal carbonyl complexes using electrospray mass spectrometry, by converting them into ions with suitable reagents. Ionisation techniques included addition of OMe generating [M 1 OMe] species, addition of Ag or Na ions giving the appropriate positive ion, abstraction of acidic hydrogen forming [M 2 H] ions, or (in rare cases) oxidation giving rad...
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The photosensitivity of metal carbonyls has been known almost as long as the class of coordination compounds itself. Among no other group of inorganic compounds may one find so many light-sensitive materials. Hence photochemical reactions of metal carbonyls have found wide applications for synthetic purposes. However, whereas much research has been done to understand the thermal reactions," the...
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ژورنال
عنوان ژورنال: Journal of Organometallic Chemistry
سال: 2018
ISSN: 0022-328X
DOI: 10.1016/j.jorganchem.2017.09.004